A single crystalline porphyrinic titanium metal–organic framework
نویسندگان
چکیده
منابع مشابه
A single crystalline porphyrinic titanium metal-organic framework.
We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal-organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford single crystals. This synthetic method is useful to obtain highly crystalline titanium MOFs, which ha...
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متن کاملA single crystalline porphyrinic titanium metal–organic framework† †Electronic supplementary information (ESI) available. CCDC [1036868]. For ESI and crystallographic data in CIF or other electronic format. See DOI: 10.1039/c5sc00916b Click here for additional data file. Click here for additional data file.
We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal–organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford single crystals. This synthetic method is useful to obtain highly crystalline titanium MOFs, which ha...
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Octahedral titanium(IV) oxide (TiO(2)) crystallites with exposed anatase [101] facets exhibited relatively high photocatalytic activity for oxidative decomposition of organic compounds and low activity for hydrogen evolution in the absence of molecular oxygen, probably due to the characteristics of the anatase [101] surface.
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2015
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c5sc00916b